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Influence of the phase structure of converter dephosphorization slag on dephosphorization

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Influence of the phase structure of converter dephosphorization slag on dephosphorization

Since the smelting of ultra-low phosphorus steels such as 9Ni has strict requirements for the final phosphorus content of the converter steelmaking, it is generally necessary to achieve a final phosphorus content of 40×10-6 in the converter. Therefore, Nangang takes pipeline steel as the research object and adopts In the double slag + slag smelting process, the phosphorus in the molten steel is mainly removed during the dephosphorization period (one pour).

The dephosphorization effect at the end of smelting is directly determined by the dephosphorization effect in the early stage of smelting. The change in the composition and phase structure of the slag during the entire smelting process of the converter reflects the melting status and slagging effect of the slag.

Scholars from University of Science and Technology Beijing used thermodynamic software Factsage6.4, SEM, EDS, XRD, combined with infrared and Raman experimental methods to analyze and study the phase structure of primary slag and terminal slag. The results showed that the viscosity of the first slag and the final slag decreased with the increase of temperature. At the same temperature, the viscosity of the first slag was higher, but the melting point was lower than that of the final slag.

There are more liquid phases formed at low temperature, which is more conducive to the progress of the dephosphorization reaction. The slag Si, Ca, P element enriched area, the main mineral phase formed is 2CaO•SiO2-3CaO•P2O5 solid solution phase, which is more beneficial to dephosphorization; while the Fe, Mn, Mg and O element enriched area is formed The main phases are iron oxide and RO phase, and the dephosphorization ability of slag is poor. Infrared and Raman analysis results show that both the first slag and the final slag form SiO4 tetrahedral units, the first slag is mainly composed of Si-O-Si bonds, and the final slag is mainly composed of P-O-P bonds. The more silicate network unit structure is, the more beneficial it is for dephosphorization.


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